Hexavalent chromium monitoring in an industrial workplace

Fume & chemical

Hexavalent Chromium Monitoring

Hexavalent chromium (Cr VI) monitoring measures exposure to a potent carcinogen produced during stainless steel welding, chrome plating and chromate coating work.

Method

MDHS 52

Sampling

Personal & static

WEL (EH40)

0.05 mg/m3 (8-hour TWA, as Cr)

Turnaround

5–10 working days

01

What is hexavalent chromium monitoring?

Hexavalent chromium monitoring measures the airborne concentration of chromium VI compounds in fume and mist from stainless steel welding, plating and chromate coatings that workers may breathe in during normal operations. It quantifies real personal exposure so employers can judge whether existing controls are adequate.

IndustrialAirMonitoring.uk provides independent hexavalent chromium monitoring across stainless steel fabrication, electroplating, coatings, aerospace, engineering sites throughout the UK. Our occupational hygienists deliver defensible exposure data that demonstrates compliance with the Control of Substances Hazardous to Health Regulations 2002 (COSHH) and the workplace exposure limits set out in HSE guidance note EH40.

02

Why hexavalent chromium monitoring matters

Under COSHH Regulation 10, employers must monitor exposure to hazardous substances where it is needed to protect health, where a workplace exposure limit could be exceeded, or where control measures need to be verified. Hexavalent chromium monitoring provides the objective evidence that satisfies this duty.

Uncontrolled exposure to hexavalent chromium is linked to lung cancer, nasal damage, dermatitis and respiratory sensitisation. Beyond the legal duty, robust monitoring protects your workforce, reduces the risk of enforcement action and civil claims, and gives insurers and clients confidence that exposure is being actively managed.

03

How we carry out hexavalent chromium monitoring

We measure exposure using filter sampling on calibrated personal pumps with Cr(VI)-specific analysis by ion chromatography, following the recognised MDHS 52 methodology. Personal samplers are worn in the breathing zone for a representative full shift to derive an 8-hour time-weighted average, while static (background) samples help map contaminant sources across the workplace.

Samples are analysed by an accredited laboratory and the results compared with the relevant occupational exposure limit. Where short-term peaks are a concern we add 15-minute short-term exposure limit (STEL) sampling, so both the chronic and acute risk picture is captured.

04

Standards, limits and reporting

The current workplace exposure limit for hexavalent chromium is 0.05 mg/m3 (8-hour TWA, as Cr) (EH40/2005, as amended). We assess compliance using the BS EN 689 statistical decision framework, which accounts for exposure variability rather than relying on a single result.

Your report sets out the measured concentrations, the compliance position, the adequacy of existing controls such as local exhaust ventilation, and a recommended re-monitoring interval. It is written to be understood by managers and to satisfy HSE inspectors, auditors and insurers.

05

Our hexavalent chromium monitoring process

Our hexavalent chromium monitoring programmes follow a structured, four-stage workflow so the results stand up to scrutiny. Request monitoring or book a site assessment to begin.

  1. 1Scoping & site survey. We review your processes, COSHH assessments and previous hexavalent chromium monitoring data, then plan a representative sampling strategy using BS EN 689 similar exposure groups.
  2. 2On-site sampling. Qualified occupational hygienists carry out calibrated breathing-zone and static measurements across a representative shift, with full chain-of-custody documentation.
  3. 3Accredited analysis. Samples are analysed using the relevant MDHS / ISO laboratory method and the results are compared against the applicable workplace exposure limit.
  4. 4Reporting & recommendations. You receive a clear exposure report with compliance status, control recommendations and a re-monitoring interval — defensible evidence for HSE, insurers and auditors.
06

Frequently asked questions

Where does hexavalent chromium come from?

Stainless steel and chrome welding fume, chrome plating mists, and the manufacture or application of chromate coatings.

How is Cr VI measured?

Air is sampled onto a filter and analysed specifically for the hexavalent species by ion chromatography to MDHS 52, distinguishing it from total chromium.

Why is Cr VI so hazardous?

It is a confirmed human carcinogen and respiratory sensitiser, so exposure must be tightly controlled and regularly monitored.

Next step

Need hexavalent chromium monitoring for your site?

Request monitoring